Fundamental Chemistry of 1,2-Dihydro-1,2-Azaborines

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dc.contributor.advisorJohnson, Darrenen_US
dc.contributor.authorLamm, Ashleyen_US
dc.creatorLamm, Ashleyen_US
dc.date.accessioned2012-12-07T23:11:16Z
dc.date.available2014-12-29T21:12:31Z
dc.date.issued2012
dc.description.abstractBenzene and its derivatives are ubiquitous in chemical research, with applications ranging from material science to biomedical research. 1,2-Dihydro-1,2-azaborine is a benzene mimic which replaces a CC bond with a BN bond. The basic science and applications of 1,2-azaborines is relatively underdeveloped. This thesis expands the fundamental understanding of 1,2-azaborines. Chapter I describes the air and moisture stability of 1,2-azaborines. Chapter II introduces nucleophilic aromatic substitution reactions that the parent 1,2-dihydro-1,2-azaborine will undergo. Chapter III discusses a trimerization reaction that 1,2-dihydro-1,2-azaborine can perform, which is unique from benzene. Chapter IV examines a novel protection free synthesis of 1,2-azaborines, which provides a more direct route to functionalized 1,2-azaborines. Chapter V discusses the novel deprotection of the N-silicon using an amide, giving one of the first 1,2-azaborine pharmaceutical mimics. Finally, chapter VI summarized miscellaneous contributions I have made to the basic science of 1,2-azaborines. This dissertation includes previously published and unpublished co-authored material.en_US
dc.description.embargo10000-01-01
dc.identifier.urihttps://hdl.handle.net/1794/12514
dc.language.isoen_USen_US
dc.publisherUniversity of Oregonen_US
dc.rightsAll Rights Reserved.en_US
dc.subjectAromaticityen_US
dc.subjectAzaborineen_US
dc.subjectBoronen_US
dc.subjectHeterocycleen_US
dc.subjectNitrogenen_US
dc.titleFundamental Chemistry of 1,2-Dihydro-1,2-Azaborinesen_US
dc.typeElectronic Thesis or Dissertationen_US

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