Geogenic Sources and Chemical Controls on Fluoride Release to Groundwater in the Independence Basin, Mexico

dc.contributor.advisorPolizzotto, Matthew
dc.contributor.authorLaFayette, Gabrielle
dc.date.accessioned2019-09-18T19:24:42Z
dc.date.available2019-09-18T19:24:42Z
dc.date.issued2019-09-18
dc.description.abstractHigh fluoride concentrations in groundwater have been revealed as an environmental health concern. Groundwater in the Independence Basin of Central Mexico reaches over an order of magnitude greater than the World Health Organization limit of 1.5 mg L-1, but sources and geochemical conditions responsible for releasing fluoride into solution are unknown. Objectives of this work determined aquifer rock types containing the greatest amounts of fluoride and investigate how changes in pH and specific conductance affect fluoride release into solution. Solid phase concentrations of fluoride in well drill cuttings displayed no apparent depth dependence, but were greatest within andesitic, alluvium, and conglomerate samples. Large amounts of fluoride were bound with metal oxides/oxyhydroxides in all samples. Batch experiments examining fluoride release from aquifer materials under evolving groundwater conditions revealed that fluoride was released into solution with elevated pH. Results here may be used to better predict fluoride contamination of aquifers.en_US
dc.identifier.urihttps://hdl.handle.net/1794/24900
dc.language.isoen_US
dc.publisherUniversity of Oregon
dc.rightsAll Rights Reserved.
dc.titleGeogenic Sources and Chemical Controls on Fluoride Release to Groundwater in the Independence Basin, Mexico
dc.typeElectronic Thesis or Dissertation
thesis.degree.disciplineDepartment of Geological Sciences
thesis.degree.grantorUniversity of Oregon
thesis.degree.levelmasters
thesis.degree.nameM.S.

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