INTERACTIONS BETWEEN TECTONISM AND MAGMATISM AT SANTORINI: INSIGHTS FROM AN ACTIVE SOURCE SEISMIC EXPERIMENT by BEN HEATH A DISSERTATION Presented to the Department of Geological Sciences and the Graduate School of the University of Oregon in partial fulfillment of the requirements for the degree of Doctor of Philosophy December 2019 DISSERTATION APPROVAL PAGE Student: Ben Heath Title: Interactions Between Tectonism and Magmatism at Santorini: Insights from an Active Source Seismic Experiment This dissertation has been accepted and approved in partial fulfillment of the requirements for the Doctor of Philosophy degree in the Department of Geological Sciences by: Emilie E. E. Hooft Chair Ilya Bindeman Core Member/Coordinator Leif Karlstrom Core Member Hank Childs Institutional Representative and Kate Mondloch Interim Vice Provost and Dean of the Graduate School Original approval signatures are on file with the University of Oregon Graduate School. Degree awarded December 2019 ii © 2019 Ben Heath All Rights Reserved iii DISSERTATION ABSTRACT Ben Heath Doctor of Philosophy Department of Geological Sciences December 2019 Title: Interactions Between Tectonism and Magmatism at Santorini: Insights from an Active Source Seismic Experiment In extensional volcanic arcs, tectonic and magmatic processes control the evolution of eruptive centers and their surrounding regions. Faulting, which increases crustal permeability, can focus magmatism and preferentially localize eruptive edifices near intersecting fault zones. In turn, magmatic diking and volcanic edifice growth/collapse can change both the regional and local stress/strain in the crust altering the style and amount of faulting. The relative importance of these magmatic and tectonic processes as well as how these processes coevolve are still poorly known. Here we study magmatic and tectonic interactions at Santorini Volcano, focusing on the localization of magmatism in the highly extended terrain and the subsequent influence of this magmatism on the evolution of tectonic activity. We use the dense PROTEUS active source seismic dataset, collected in a 120 km x 45 km region around the volcano, to perform both P-wave anisotropic traveltime tomography inversions and full waveform inversions, imaging the upper crust down to ∼4 km depth. Integrating our results with the well-studied volcanic and geologic history of Santorini, we show evidence for strong tectonic control on the evolution of Santorini’s magmatic system. In Chapter II and V, this interaction is recorded as i) the alignment of volcanic features parallel to tectonic features, ii) the localization of volcanism within a tectonic basin, and iii) the strong influence of tectono-magmatic lineaments on both regional volcanic evolution and localization iv of caldera collapse. In Chapter III we show that the magnitude of small-scale local faulting is uncorrelated to regions of magmatic activity indicating that magmatism is neither focused in areas of higher fracturing nor is accommodating substantial extensional strain. Rather both magmatism and small-scale faulting are strongly correlated with regional stress. In Chapter IV we hypothesize that the broad distribution of deformation (>40 km wide) currently observed results from magmatic activity. In contrast, a narrower episode of localized deformation (<20 km wide) preceded initiation of regional magmatism. This highlights the impact of regional magmatism on tectonic evolution. This works shows that magmatic and tectonic processes interact on a variety of temporal and spatial scales. This dissertation includes both previously published and co-authored material. v CURRICULUM VITAE NAME OF AUTHOR: Ben Heath GRADUATE AND UNDERGRADUATE SCHOOLS ATTENDED: University of Oregon, Eugene, OR, USA Northwestern University, Evanston, IL, USA DEGREES AWARDED: Doctor of Philosophy, Geological Sciences, 2019, University of Oregon Master of Science, Geological Sciences, 2014, University of Oregon Bachelor of Arts, Earth and Planetary Sciences, 2012, Northwestern University AREAS OF SPECIAL INTEREST: Geophysics/Seismology Volcanology Tectonophysics PROFESSIONAL EXPERIENCE: Graduate Student, University of Oregon 2015-2019 ORISE Fellow, NETL-Albany 2015-2015 Graduate Student, University of Oregon 2012-2014 GRANTS, AWARDS AND HONORS: Johnston Memorial Fellowship, 2012 Johnston Geology Fund, 2015, 2016, 2017 Weiser Memorial Scholarship, 2016, 2017 Outstanding Student Presentation Award, IAVCEI 2017 GSA Student Research Grant, 2017 PUBLICATIONS: Heath, B. A., Hooft, E. E. E., Toomey, D. R., Papazachos, C. B., Nomikou, P., Paulatto, M., Morgan, J.V., & Warner, M.R. (2019). Tectonism and its relation to magmatism around Santorini volcano from upper crustal P-wave velocity. Journal of Geophysical Research: Solid Earth DOI: https://doi.org/10.1029/2019JB017699 vi Hooft, E.E.E., Heath, B.A., Toomey, D.R., Paulatto, M., Papazachos, C.B., Nomikou, P., Morgan, J.V., & Warner, M.R. (2019). Seismic imaging of Santorini: Subsurface constraints on caldera collapse and present-day magma recharge. Earth and Planetary Science Letters, 514, 48-61. DOI: https://doi.org/10.1016/j.epsl.2019.02.033 Hooft, E. E. E., Nomikou, P., Toomey, D. R., Lampridou, D., Getz, C., Christopoulou, M. E., O’Hara, D., Arnoux, G. M., Bodmer, M., Gray, M., Heath, B. A., & VanderBeek, B. P. (2017). Backarc tectonism, volcanism, and mass wasting shape seafloor morphology in the Santorini- Christiana-Amorgos region of the Hellenic Volcanic Arc. Tectonophysics, 712, 396-414. DOI: https://doi.org/10.1016/j.tecto.2017.06.005 Heath, B. A., Hooft, E. E., & Toomey, D. R. (2018). Autocorrelation of the seismic wavefield at Newberry Volcano: Reflections from the magmatic and geothermal systems. Geophysical Research Letters, 45(5), 2311-2318. DOI: https://doi.org/10.1002/2017GL076706 Mark-Moser, M. K., Rose, K. K., Schultz, J. D., Schultz, A., Heath, B., Urquhart, S., & Vincent, P. (2015). A Conceptual Geologic Model for the Newberry Volcano EGS Site in Central Oregon: Constraining Heat Capacity and Permeability Through Joint Interpretation of Multifaceted Geophysical and Geological Data Sets (No. NETL-PUB-20152). NETL. Heath, B. A., Hooft, E. E., Toomey, D. R., & Bezada, M. J. (2015). Imaging the magmatic system of Newberry Volcano using joint active source and teleseismic tomography. Geochemistry, Geophysics, Geosystems, 16(12), 4433-4448. DOI: https://doi.org/10.1002/2015GC006129 vii ACKNOWLEDGEMENTS I would first like to acknowledge my parents who have been supportive of me throughout my graduate career. Without their help, I am not sure how I would have finished this degree. I would like to thank my advisor Emilie Hooft for both giving me an opportunity to work on the PROTEUS dataset as well as for providing me the space to develop and test my ideas. I would also like to thank my collaborators during this experiment including: Emilie Hooft, Joanna Morgan, Paraskevi Nomikou, Costas Papazachos, Michele Paulatto, Doug Toomey and Mike Warner. Their feedback throughout this process has been invaluable. I am indebted to Kajetan Chrapkiewicz and Brennah McVey for helpful conversations regarding Santorini. I would like to thank my committee which consists of Emilie Hooft, Ilya Bindeman, Leif Karlstrom, and Hank Childs. I appreciate the support they provided, their honest and open feedback, and their constructive criticism which has helped me to become a better scientist. My views on and understanding of magmatic systems has been shaped by conversations with a wide range of people. The patience displayed by the volcanology community in explaining concepts to a young scientist is greatly appreciated. I would like to thank my roommates, labmates and friends over the past few years for their support. I feel honored to have gone through my graduate career with so many bright people by my side. Much of my research has used super-computers present on the University of Oregon campus. I am constantly amazed by both my ability to make mistakes viii in the job submission process and the responsiveness of the ACISS/talapas high performance computing team to my frantic cries for help. Without this team, I would still be submitting “hello world” jobs to as many computer nodes as possible. Finally, I would like to thank the Department of Earth Sciences (formerly the Department of Geological Sciences or DoGS), especially the office staff, Marla, Sandy and Dave. ix To my parents, thank you for always supporting me and helping me to become a better person x TABLE OF CONTENTS Chapter Page I. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . 1 II. TECTONISM AND ITS RELATION TO MAGMATISM AROUND SANTORINI VOLCANO FROM UPPER CRUSTAL P-WAVE VELOCITY . . . . . . . . . . . . . . . . . . 5 2.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 5 2.2. Background . . . . . . . . . . . . . . . . . . . . . . . 6 2.2.1. Tectonic background . . . . . . . . . . . . . . . . . . 6 2.2.2. Volcanic Background . . . . . . . . . . . . . . . . . . 11 2.3. Experiment Geometry and Data Acquisition . . . . . . . . . 12 2.3.1. Seismic experiment . . . . . . . . . . . . . . . . . . . 12 2.3.2. Data return and data quality . . . . . . . . . . . . . . . 13 2.4. Data processing and tomographic inversion . . . . . . . . . . 14 2.4.1. OBS relocation . . . . . . . . . . . . . . . . . . . . . 14 2.4.2. Pg travel time data . . . . . . . . . . . . . . . . . . . 15 2.4.3. Tomographic Inversion . . . . . . . . . . . . . . . . . . 16 2.5. Results and Interpretation . . . . . . . . . . . . . . . . . 19 2.5.1. Upper crustal velocity variations . . . . . . . . . . . . . 19 2.5.2. Comparison of tomographic velocity model with seismic reflection images . . . . . . . . . . . . . . . . . 20 2.5.3. Mapping geometry and thickness of sedimentary basins from the tomography model . . . . . . . . . . . . 23 2.5.4. Western side of Santorini: Christiana Basin and Christiana Ridge . . . . . . . . . . . . . . . . . . . . 24 2.5.5. Eastern side of Santorini: Anydros Basin, Anafi Basin and Anydros Horst . . . . . . . . . . . . . . . . 27 2.5.6. Structures associated with Santorini . . . . . . . . . . . . 28 xi Chapter Page 2.6. Discussion . . . . . . . . . . . . . . . . . . . . . . . . 29 2.6.1. Differences between the east and west sides of Santorini and relationship to faulting . . . . . . . . . . . 29 2.6.2. Tectonic evolution of the basins and Christiana- Santorini-Kolumbo magmatism: Localization of magma in a proto-Anydros Basin . . . . . . . . . . . . . 32 2.6.3. Volcano-tectonic lineaments . . . . . . . . . . . . . . . 35 2.7. Conclusions . . . . . . . . . . . . . . . . . . . . . . . 36 2.8. Bridge . . . . . . . . . . . . . . . . . . . . . . . . . . 37 III. RELATIONSHIP BETWEEN FAULTING AND MAGMATISM AROUND SANTORINI: SEISMIC ANISOTROPY RESULTS FROM A REFRACTION EXPERIMENT . . 39 3.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 39 3.2. Background . . . . . . . . . . . . . . . . . . . . . . . 41 3.2.1. Geologic Background of the Aegean . . . . . . . . . . . . 41 3.2.2. Regional Volcanism and its Relation to Tectonics . . . . . . 43 3.2.3. Current State of Tectonic and Magmatic Activity . . . . . . 45 3.3. Methods . . . . . . . . . . . . . . . . . . . . . . . . . 46 3.3.1. Tomography . . . . . . . . . . . . . . . . . . . . . . 46 3.3.2. Forward Modeling . . . . . . . . . . . . . . . . . . . . 48 3.4. Results . . . . . . . . . . . . . . . . . . . . . . . . . 51 3.4.1. Tomographic Results . . . . . . . . . . . . . . . . . . 51 3.4.2. Forward Modeling Anisotropy Results . . . . . . . . . . . 57 3.5. Discussion . . . . . . . . . . . . . . . . . . . . . . . . 63 3.5.1. Source of Anisotropy on the eastern side of Santorini . . . . 63 3.5.2. Modeling the fraction of different aspect ratio fractures . . . 66 3.5.3. Magmatism and its relationship to faulting/fracturing around Santorini - Local- scale/Regional Scale Interactions . . . . . . . . . . . . . 68 xii Chapter Page 3.5.4. Implications for Sources of Faulting and Fault Damage Zones on the Eastern Side of Santorini . . . . . . . 73 3.5.5. Understanding the Regional Tectonic and Magmatic Interactions . . . . . . . . . . . . . . . . . . 77 3.6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . 79 3.7. Bridge . . . . . . . . . . . . . . . . . . . . . . . . . . 80 IV. TECTONISM AND THE INFLUENCE OF INHERITED STRUCTURAL DEFORMATION AROUND SANTORINI FROM P-WAVE TOMOGRAPHY . . . . . . . . . . . . . . . . . 81 4.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 81 4.2. Background . . . . . . . . . . . . . . . . . . . . . . . 83 4.3. Methods . . . . . . . . . . . . . . . . . . . . . . . . . 86 4.4. Results . . . . . . . . . . . . . . . . . . . . . . . . . 91 4.4.1. Overview of seismic anisotropy results from travel-time tomography . . . . . . . . . . . . . . . . . 91 4.4.2. Overview of FWI results . . . . . . . . . . . . . . . . . 93 4.4.3. Comparison of FWI results to isotropic travel- time tomography results . . . . . . . . . . . . . . . . . 97 4.4.4. Comparison of FWI to seismic reflection results . . . . . . . 99 4.5. Discussion . . . . . . . . . . . . . . . . . . . . . . . . 100 4.5.1. Seismic anisotropy and the record of ductile deformation . . . 100 4.5.2. Tomographic evidence of brittle behavior in the Christiana Basin . . . . . . . . . . . . . . . . . . . . 105 4.5.3. Distribution of faulting within and outside the basin proper . . . . . . . . . . . . . . . . . . . . . . 108 4.5.4. Ductile and brittle deformation: controls on the localization of deformation, comparison between east and west . . . . . . . . . . . . . . . . . . . . . . 114 4.6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . 118 4.7. Bridge . . . . . . . . . . . . . . . . . . . . . . . . . . 121 xiii Chapter Page V. SEISMIC IMAGING OF SANTORINI: SUBSURFACE CONSTRAINTS ON CALDERA COLLAPSE AND PRESENT-DAY MAGMA RECHARGE . . . . . . . . . . . . . . . 122 5.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 122 5.2. Santorini volcano . . . . . . . . . . . . . . . . . . . . . 124 5.3. Seismic experiment and data . . . . . . . . . . . . . . . . 129 5.4. Tomographic inversion and results . . . . . . . . . . . . . 130 5.4.1. Inversion . . . . . . . . . . . . . . . . . . . . . . . . 130 5.4.2. Synthetic tomography resolution tests . . . . . . . . . . . 133 5.4.3. Tomography results . . . . . . . . . . . . . . . . . . . 134 5.5. Calculation of physical properties . . . . . . . . . . . . . . 135 5.6. Discussion . . . . . . . . . . . . . . . . . . . . . . . . 139 5.6.1. Collapse plug filled with volcanic deposits . . . . . . . . . 143 5.6.2. Phreatomagmatic rock breakup . . . . . . . . . . . . . . 144 5.6.3. Multistage, nested caldera collapse . . . . . . . . . . . . 145 5.6.4. Present day magma recharge . . . . . . . . . . . . . . . 147 5.7. Conclusions . . . . . . . . . . . . . . . . . . . . . . . 150 VI. CONCLUSIONS . . . . . . . . . . . . . . . . . . . . . . . . . 152 APPENDICES A. APPENDIX CHAPTER II: TECTONISM AND ITS RELATION TO MAGMATISM AROUND SANTORINI VOLCANO FROM UPPER CRUSTAL P-WAVE VELOCITY . . . . . 155 A.1. Description of Synthetics . . . . . . . . . . . . . . . . . 155 A.2. Attenuation of caldera centered data . . . . . . . . . . . . 168 A.3. First motions of signals . . . . . . . . . . . . . . . . . . 168 A.4. 1-D velocity profile comparison . . . . . . . . . . . . . . . 168 A.5. Investigations of roughness/smoothing values vs RMS of travel time residuals . . . . . . . . . . . . . . . . 168 xiv Chapter Page A.6. Dv analysis as function of penalty and smoothing . . . . . . . 168 A.7. Checkerboard test: 5x5x2 km checkers . . . . . . . . . . . . 168 A.8. Checkerboard test:5x5x1 km checkers . . . . . . . . . . . . 168 A.9. Checkerboard test: 3x3x1 km checkers . . . . . . . . . . . . 168 A.10. MCS comparison Supplement 1 . . . . . . . . . . . . . . . 168 A.11. MCS comparison Supplement 2 . . . . . . . . . . . . . . . 168 A.12. Contouring basin depth using various different velocities . . . . 168 A.13. Evidence for anisotropy in traveltime residuals . . . . . . . . 168 A.14. RMS of travel times for various different parameters . . . . . . 168 B. APPENDIX CHAPTER III: RELATIONSHIP BETWEEN FAULTING AND MAGMATISM AROUND SANTORINI: SEISMIC ANISOTROPY RESULTS FROM A REFRACTION EXPERIMENT . . . . . . . . . . . . . . . . . . 169 B.1. Calculation of Resolution of Anisotropy . . . . . . . . . . . 169 B.2. Applicability of Anisotropy Assumptions . . . . . . . . . . . 169 C. APPENDIX CHAPTER IV: TECTONISM AND THE INFLUENCE OF INHERITED STRUCTURAL DEFORMATION AROUND SANTORINI FROM P-WAVE TOMOGRAPHY . . . . . . . . . . . . . . . . . . . . . . . . . 172 C.1. Modeling Anisotropy . . . . . . . . . . . . . . . . . . . 172 C.2. Modeling Styles of Extension . . . . . . . . . . . . . . . . 176 D. APPENDIX CHAPTER V: SEISMIC IMAGING OF SANTORINI: SUBSURFACE CONSTRAINTS ON CALDERA COLLAPSE AND PRESENT-DAY MAGMA RECHARGE . 178 D.1. Temperature and pressure corrections for velocity . . . . . . . 178 D.2. Checkerboard resolution test . . . . . . . . . . . . . . . . 179 D.3. Cylindrical low-velocity anomaly resolution test . . . . . . . . 179 D.4. Comparison of shallow tomography velocity model with seismic reflection profiles . . . . . . . . . . . . . . . 179 D.5. Comparison of shallow tomography velocity model with seismic reflection profiles . . . . . . . . . . . . . . . 179 xv Chapter Page D.6. Interpretation of the low VP anomaly if porosity were filled with partial melt . . . . . . . . . . . . . . . . 179 REFERENCES CITED . . . . . . . . . . . . . . . . . . . . . . . . 184 xvi LIST OF FIGURES Figure Page 2.1. Tectonic setting of the Aegean . . . . . . . . . . . . . . . . . . 7 2.2. Experiment geometry and regional tectonic structures . . . . . . . . 10 2.3. Example of seismic data from two basins . . . . . . . . . . . . . . 14 2.4. Regional 1-D P-wave velocity-depth profiles . . . . . . . . . . . . 18 2.5. Tomographic velocity anomalies . . . . . . . . . . . . . . . . . . 19 2.6. Regional cross section locations . . . . . . . . . . . . . . . . . . 21 2.7. Comparison with seismic reflection profiles . . . . . . . . . . . . . 23 2.8. Analysis of regional basin depths . . . . . . . . . . . . . . . . . 25 2.9. Cross sections through the velocity model . . . . . . . . . . . . . 26 2.10. Comparison between caldera centered geology and tomographic velocity anomalies . . . . . . . . . . . . . . . . . . 30 2.11. Model of tectonic evolution . . . . . . . . . . . . . . . . . . . . 33 3.1. Regional tectonic setting and experiment geometry . . . . . . . . . 42 3.2. Azimuthal distribution of travel-time residuals: evidence for anisotropy . . . . . . . . . . . . . . . . . . . . . . . . . 52 3.3. Anisotropic structure of the eastern portion of the experiment . . . . 54 3.4. Anisotropic depth distribution . . . . . . . . . . . . . . . . . . 55 3.5. Anisotropy magnitudes across the experiment . . . . . . . . . . . . 57 3.6. Calculation of the effect of dikes on seismic velocity . . . . . . . . . 59 3.7. Calculation of the effect of fractures on seismic velocity . . . . . . . 61 3.8. Calculation of the effect of dipping faults on seismic velocity . . . . . 63 3.9. Calculation of combined fracture-induced anisotropy with metamorphic-structure derived anisotropy . . . . . . . . . . . . . 64 3.10. Regional overview of fracture distribution . . . . . . . . . . . . . 68 xvii Figure Page 3.11. Hypotheses relating tectonism and magmatism . . . . . . . . . . . 71 3.12. Interpretations of regional structure . . . . . . . . . . . . . . . . 74 4.1. Recorded and modeled waveforms . . . . . . . . . . . . . . . . . 88 4.2. Phase residual comparison between final and starting model . . . . . 92 4.3. Comparison of ideal and actual coverage for FWI inversions . . . . . 93 4.4. Anisotropic travel-time tomography for various depths . . . . . . . . 94 4.5. FWI results for various depth slices . . . . . . . . . . . . . . . . 95 4.6. Cross sections through the FWI models . . . . . . . . . . . . . . 96 4.7. Overview of cross sections and regions used for averaging velocities . . 98 4.8. Comparison between FWI and traveltime tomography . . . . . . . . 99 4.9. Comparison of FWI to seismic reflection studies: example 1 . . . . . 101 4.10. Comparison of FWI to seismic reflection studies: example 2 . . . . . 102 4.11. Anisotropy resulting from metamorphic horst properties . . . . . . . 106 4.12. Anisotropy distribution for various geologically motivated blocks . . . 110 4.13. Orientation of anisotropy throughout the experiement . . . . . . . . 111 4.14. Hypothesis 1: Wide rifting from thermal perturbations . . . . . . . 117 4.15. Hypothesis 2: Accommodation zones and their effect on distributed faulting . . . . . . . . . . . . . . . . . . . . . . . 119 4.16. Model of regional evolution . . . . . . . . . . . . . . . . . . . . 120 5.1. PROTEUS seismic experiment map . . . . . . . . . . . . . . . . 124 5.2. The geological and volcanic features of Santorini . . . . . . . . . . 127 5.3. Maps of P-wave seismic velocity at Santorini . . . . . . . . . . . . 131 5.4. Cross-sections of seismic velocity along profile A-A’ and B-B’ . . . . . 132 5.5. Predicted porosity for the northern caldera low-velocity anomaly and the reference metamorphic profile. . . . . . . . . . . . 136 5.6. Conceptual model for the evolution of the LBA eruption and formation of the low-velocity anomaly. . . . . . . . . . . . . . 142 xviii Figure Page 5.7. Comparison of the low-velocity anomaly with magma recharge during the 2011-2012 unrest and predicted lithostatic pressure at 4 km depth. . . . . . . . . . . . . . . . . 149 A.1. Attenuation of caldera centered data . . . . . . . . . . . . . . . 156 A.2. First motions of signals . . . . . . . . . . . . . . . . . . . . . 157 A.3. 1-D velocity profile comparison . . . . . . . . . . . . . . . . . . 158 A.4. Investigations of roughness/smoothing values vs RMS of travel time residuals . . . . . . . . . . . . . . . . . . . . . . . 159 A.5. Dv analysis as function of penalty and smoothing . . . . . . . . . . 160 A.6. Checkerboard test: 5x5x2 km checkers . . . . . . . . . . . . . . . 161 A.7. Checkerboard test:5x5x1 km checkers . . . . . . . . . . . . . . . 162 A.8. Checkerboard test: 3x3x1 km checkers . . . . . . . . . . . . . . . 163 A.9. MCS comparison Supplement 1 . . . . . . . . . . . . . . . . . . 164 A.10. MCS comparison Supplement 2 . . . . . . . . . . . . . . . . . . 165 A.11. Contouring basin depth using various different velocities . . . . . . . 166 A.12. Evidence for anisotropy in traveltime residuals . . . . . . . . . . . 167 B.1. Approximating anisotropy using a weak elastic assumption . . . . . . 170 B.2. Predicted velocities and travel-times as a function of azimuth for various different magnitudes of anisotropy . . . . . . . . 171 D.1. Checkerboard resolution test . . . . . . . . . . . . . . . . . . . 180 D.2. Cylindrical low-velocity anomaly resolution test . . . . . . . . . . . 181 D.3. Comparison of shallow tomography velocity model with seismic reflection profiles. . . . . . . . . . . . . . . . . . . . . 181 D.4. Comparison of shallow tomography velocity model with seismic reflection profiles. . . . . . . . . . . . . . . . . . . . . 182 D.5. Interpretation of the low VP anomaly if porosity were filled with partial melt . . . . . . . . . . . . . . . . . . . . . . 183 xix LIST OF TABLES Table Page 4.1. Data Processing Steps . . . . . . . . . . . . . . . . . . . . . . . 87 4.2. Model Parameters . . . . . . . . . . . . . . . . . . . . . . . . . 89 4.3. Inversion Parameters . . . . . . . . . . . . . . . . . . . . . . . 90 A.1. RMS of travel times for various different parameters . . . . . . . . . . 168 C.1. Extensional Style Parameters . . . . . . . . . . . . . . . . . . . . 177 xx CHAPTER I INTRODUCTION Globally, magmatic centers are found to strongly correlate with areas of tectonic activity on a variety of spatial scales. Volcanic cones form linear alignments that parallel the local kilometer-scale fault orientations, larger volcanic edifices often lie near the intersection of multiple fault zones and at volcanic-arc scales magmatic eruption volume is found to correlate with extension rate (e.g. Muirhead et al., 2015; MacLeod and Sherrod, 1988; Acocella and Funiciello, 2010). This interaction is commonly attributed to tectonic faults providing pathways for the ascent of both magma and magmatic fluids as well as due to tectonic stresses localizing magmatic activity (e.g. Kokkalis and Aydin, 2013; Magee et al., 2013). Magmatism can then change tectonic activity by i) accommodating extensional strain and modifying crustal stresses, which change fault density and orientation and ii) weakening the crust through thermal and physical effects (e.g. Parsons and Thompson, 1991; Parsons and Thompson, 1993; Casey et al., 2006; Ebinger and Casey, 2001, Corti et al., 2013). However, despite strong evidence for interaction, in many volcanic systems it is not clear whether tectonic or magmatic stresses dominate regional evolution. This is further complicated because the interaction between these two processes evolves through both time and space, as the thermal and physical properties of the crust change through the addition of magma/magmatic fluids. While there is a substantial body of work investigating these tectonic and magmatic interactions, studies have historically been limited by several issues. Geologic studies, which are limited to the surface expression of faults and volcanic deposits, have been biased against features that exist at depth and are limited to rocks present in exposures. Geophysical methods, which are designed to probe the 1 current state of upper crustal continental magmatic systems, have been historically of too poor resolution to sufficiently resolve local-scale tectonic and magmatic interactions and have only been able to image regional faults. Due to the ease of data collection in marine settings over land settings, the best studied volcanoes from a seismic tomography perspective are preferentially located in the ocean. It is precisely these oceanic regions that are inherently undersampled in geologic studies due to limited outcrops and as a results are few volcanoes that are well studied both geophysically and geologically. Therefore, few studies are able to combine well-mapped geologic observations with dense geophysical constraints without sacrificing resolution from either technique. Here I probe upper crustal tectonic and magmatic interactions in the marine setting of Santorini Volcano, Greece by combining both anisotropic P- wave travel-time tomography and Full Waveform Inversions (FWI) with a well- studied geologic history. Santorini, which sits on extended Aegean crust, is a prime location to study tectonic and magmatic interactions because it has experienced multiple episodes and styles of tectonic extension that were both accompanied and unaccompanied by magmatism, it has a well-studied geologic and geochemical record and history outlining episodes of both tectonism and magmatism and it is located in a marine setting enabling the collection of dense active source seismic experiment which provides unprecedented resolution of the continental upper crust. By combining the geophysical results with geological and geochemical studies, we are able to resolve deeper features, record subtle interactions between tectonic and magmatic activity and build/test conceptual models of the timescales, length-scales and styles of tectonic and magmatic interactions. Chapter II provides a regional overview of faults and magmatic features imaged using a dense marine-land seismic experiment. In this chapter, I conducted 2 isotropic P-wave travel-time tomography inversions to resolve seismic velocity and ultimately resolve crustal structure beneath Santorini and the surrounding region. This chapter validates the structures interpreted in later chapters, outlines broad tectonic and magmatic interactions around Santorini including volcano-tectonic lineaments that have focused regional volcanism and proposes a regional model for tectonic evolution. This chapter was published with coauthors E. E. E. Hooft, D. R. Toomey, C.B. Papazachos, P. Nomikou, M. Paulatto, J.V. Morgan, M.R. Warner in Journal of Geophysical Research in a paper titled “Tectonism and its relation to magmatism around Santorini volcano from upper crustal P-wave velocity." Chapter III discusses anisotropic travel-time inversion results for the Santorini-Kolumbo region, a region inclusive of both the large Santorini caldera and the nearby, submerged Kolumbo volcano. Here I investigate the localization of magmatism in this region from local and regional faults. Anisotropic travel time results resolve local, small, kilometer-scale fault structure, providing the first tomographic insight into small-scale interaction between magmatism and tectonic activity at Santorini. Using a model that relates observed seismic velocity and anisotropy to fault fraction and orientation, I show that regions of magmatism have no correlation to the magnitude of local-scale faulting but do have a strong relationship to regional-scale faulting, indicating that small scale faults are not a first order control on magmatic activity. These results show that the regional structure on the eastern side of Santorini is characterized by pervasive local faulting and that regional extension has provided a favorable stress regime to allow the rise of magmatic fluids. Chapter IV investigates the largely amagmatic Christiana basin (western side of Santorini) using anisotropic travel-time tomography and FWI, outlining the style of extension in the Christiana basin in order to understand a transition 3 from narrow amagmatic extension within the basin to broader magmatic extension observed regionally. I investigate sources of seismic anisotropy here and show that it results from a variety of different processes including various oriented faults from differing extensional episodes as well as ductile-deformation-derived metamorphic stretching lineations that record prior Oligo-Miocene extension. Using FWI, I outline the regional tectonic fault structure of the Christiana basin and investigate localization of faulting within the basin proper, inferring changes in the orientation of faulting through time. The differences between older amagmatic localized faulting within the Christiana basin and younger, distributed NE-SW oriented faults associated with magmatism (discussed in Chapters II and III) is hypothesized to be caused by thermal perturbations to the crust resulting from initiation of magmatism. I provide an overview of different extensional modes and their evolution through time. Chapter V consists of a focused P-wave travel-time tomography study of the structure of the Santorini caldera, highlighting the localization of vents around a newly discovered region of isolated caldera collapse which in turn is localized between two long-lived tectono-magmatic structures. This chapter, titled “Seismic imaging of Santorini: Subsurface constraints on caldera collapse and present-day magma recharge" was written by EEE Hooft, and coauthored by Heath, B.A., Toomey, D.R., Paulatto, M., Papazachos, C.B., Nomikou, P., Morgan, J.V. and Warner, M.R. and is published in the journal Earth and Planetary Sciences. This work is included in this dissertation as B. A. Heath collected all the travel-times used in this project, conducted all tomographic inversions and contributed to the development of ideas presented. 4 CHAPTER II TECTONISM AND ITS RELATION TO MAGMATISM AROUND SANTORINI VOLCANO FROM UPPER CRUSTAL P-WAVE VELOCITY This chapter was published in Journal of Geophysical Research: Solid Earth, under the title “Tectonism and its relation to magmatism around Santorini volcano from upper crustal P-wave velocity.” This publication was co-authored with E. E. E. Hooft, D. R. Toomey, C.B. Papazachos, P. Nomikou, M. Paulatto, J.V. Morgan, M.R. Warner. Ben Heath picked the data used in this chapter, conducted all the inversions, wrote the paper and drafted all figures. All co-authors contributed to discussion of ideas and provided extensive edits to the document. 2.1 Introduction In extensional volcanic arcs, the crust is often composed of a patchwork of interacting faults that control the localization of magmatism and development of sedimentary basins. Analogue models have shown that magma may be localized within basins in different extensional regimes (Corti et al., 2003). In turn magma bodies can alter the stress state of the crust. In addition to weakening the crust through thermal effects, magmatism can facilitate the formation of low angle faults (Parsons & Thompson, 1993), inhibit the formation of through-going normal faults (e.g., Faulds & Varga, 1998), and accommodate extensional strain. Santorini is one of the most active volcanoes in the Hellenic Volcanic arc (e.g., Le Pichon & Angelier, 1979) (Figure 2.1), resulting from the subduction of the African plate under the Aegean microplate. Regional extension, since the Oligocene-Miocene, has been accommodated both on older E-W oriented faults and on younger NE-SW oriented normal faults that remain tectonically active to present day. As a consequence of this extension, the crust has been thinned and 5 multiple fault systems of differing orientations intersect Santorini (Figures 2.1 and 2.2). The link between tectonics and magmatism across Santorini, however, is currently not well constrained, in part because many of these features are buried under sedimentary and volcanic deposits. In this study we use seismic data, acquired in the marine-land active- source PROTEUS (Plumbing Reservoirs Of The Earth Under Santorini) seismic experiment, to obtain a tomographic P-wave velocity model of the upper-crustal structure across Santorini volcano and the surrounding region. Seismic velocity is sensitive to fracturing, porosity, and composition and, here, we use it to delineate the structure and evolution of faults, extensional basins, as well as volcanic features in the Santorini region. We draw on our tomographic images, and results from previous seismic reflection and other studies, to delineate basins and faults. The combined datasets, as well as results from prior studies, are used to investigate differences between the upper crust to the west and east of Santorini, build a geologic model of fault evolution, and explore the relationship between tectonism and magmatism. 2.2 Background 2.2.1 Tectonic background The Aegean has undergone multiple episodes of extension from at least the Oligocene-Miocene to present that were driven by slab roll-back of the Hellenic subduction zone (Le Pichon & Angelier, 1979), westward extrusion of Anatolia (McKenzie, 1972), and gravitational collapse of continental crust (McKenzie, 1972). These extensional events have led to thinned crust (Makris, 1976, 1978), exhumed and rotated metamorphic blocks (e.g. Walcott & White, 1998), and localized 6 20˚ 22˚ 24˚ 26˚ 28˚ 30˚ 32˚ 34˚ 36˚ 38˚ 40˚ 42˚ Methana Milos Santorini Nisyros&Kos ~30 m m /yr Aegean Greece Turkey Africa Hellenic Trough North Anatolia Fault Cyclades Anatolia Crete Cretan Basin Eastern Aegean volcanic arc volcano study area approximate gps velocity Figure 2.1. Tectonic setting of the Aegean. Topographic/bathymetric map of the broader Aegean/Hellenic subduction zone (bold grey line with triangles) where the African plate subducts under the Aegean microplate showing the volcanic arc (red region) and main volcanic centers (stars and bold names). The study area is indicated with a dashed box. Faults in the overriding Aegean microplate (black lines, after Caputo et al., 2012) result from subduction rollback and extrusion along the North Anatolia Fault. The Santorini study area is located between the Cyclades to the northwest and the Cretan Basin to the south, within an actively faulted region. The GPS-derived velocity vectors relative to Eurasia (black arrows) reflect differential motion between regions east and west of Santorini (Reilinger et al., 2010). 7 deformation along zones of crustal weakness (Jolivet et al., 2013 and citations therein), creating a variety of deforming terrains. Geological studies show that the Cyclades (Figure 2.1) were extended, thinned, and rotated throughout the Miocene, but have behaved as a single rotating block since the late Miocene-early Pliocene (Walcott & White, 1998) and currently exhibit little internal deformation. Santorini and the surrounding region lies at the southeastern margin of this Cycladic block (Le Pichon & Kreemer, 2010) (Figure 2.1). During the Miocene to Pliocene, E-W-striking normal faults and related basins formed under ~N-S extension (Anastasakis & Piper, 2005; Piper et al., 2007). One of these basins is the Christiana basin in the western part of the study area. The Christiana basin has been mapped using seismic reflection imaging (Tsampouraki-Kraounaki & Sakellariou 2018, Piper et al., 2007 and citations therein) and is thought to have been truncated against N-S-striking transfer faults (Piper & Perissoratis, 2003). This E-W-striking basin is filled with Messinian and younger sediments (Piper & Perissoratis, 2003, Tsampouraki-Kraounaki & Sakellariou 2018). The main faults bounding the Christiana basin ceased activity ~1 Ma during the Pleistocene (Piper and Perissoratis, 2003) but some activity continues to present day as evidenced by small-offset, active faults observed in seismic reflection data (Tsampouraki-Kraounaki & Sakellariou, 2018). In the latest Pliocene or early Pleistocene, the regional stress direction rotated resulting in NE-SW trending faults and subsequent basin inversion (Piper and Perissoratis, 2003; Piper et al., 2007) as well as the formation of new basins such as the Anydros and Anafi Basins on the eastern side of our study area (e.g., Hübscher et al., 2015; Nomikou et al., 2016). Following the change in 8 faulting orientation, volcanism in the region began (Perissoratis, 1995), with initial volcanism sourced at Christiana and Akrotiri (SW Santorini) (Piper et al., 2007). Faults striking NE-SW continue to be active to present day (e.g., Dimitriadis et al., 2009, Bohnhoff et al., 2006) and are thought to be predominately extensional to trans-tensional (Hubscher et al., 2015, Hooft et al., 2017, Nomikou et al., 2016, Nomikou et al., 2018), but a component of strike-slip behavior is observed (Sakellariou et al., 2010). The NE-SW-striking Santorini-Amorgos fault zone (e.g. Stiros et al., 1994), which includes the Anydros Region on the eastern side of the study area (Figure 2.2), is one of the most active in the Aegean and regionally is the margin between the seismically quiet Cycladic block and the diffuse seismicity observed in the eastern Aegean (Bohnhoff et al., 2006). This is consistent with GPS studies showing that the eastern Aegean moves to the SE relative to the Cylcadic block (McClusky et al., 2000; Reilinger et al., 2010). Metamorphosed sediments of the Attico-Cycladic complex, which were exhumed during Miocene and younger extension (Piper et al., 2007; Piper & Perissoratis, 2003; Xypolias et al., 2010), highlight the role of tectonics in the evolution of the southern Aegean. These exhumed rocks compose most of the regional islands (e.g. Ios, Amorgos) ( Lister et al., 1984; Forster et al., 1999), including a portion of SW Santorini itself (Heiken & Mccoy, 1984). Moreover, these metamorphic fault blocks often extend as horsts into the Aegean sea, as seen in sea bathymetry and seismic reflection profile images (Perissoratis, 1995; Hübscher et al., 2015; Nomikou et al., 2016; 2018; Hooft et al., 2017). Metamorphic basement lithics, found in the erupted ignimbrite products from Santorini, reveal that the metamorphic complex must underlie Santorini’s caldera (Druitt, 2014) and it is thought that Santorini sits on a NE-SW oriented fracture network (Budetta et al., 1984). 9 25˚00' 25˚00' 25˚15' 25˚15' 25˚30' 25˚30' 25˚45' 25˚45' 26˚00' 26˚00' 36˚15' 36˚15' 36˚30' 36˚30' 36˚45' 36˚45' 25˚00' 25˚00' 25˚15' 25˚15' 25˚30' 25˚30' 25˚45' 25˚45' 26˚00' 26˚00' 36˚15' 36˚15' 36˚30' 36˚30' 36˚45' 36˚45' −1400 −1200 −1000 −800 −600 −400 −200 0 200 400 Kameni Islands Amorgos B asin Christiana Basin (CB) Anydro s H orst (A H) Ana� Basin (AFB) Christiana Akrotiri Anydros B asin (A B) Santorini Ana� Ios Ios f ault z one (IF ) Anydros Amorgos Sea of Crete Ak ro tir i fa ul t Santorini Ana� Basin (SAB) Ana� Amorgos Basin (AAB) Kolumbo Volca nic Chain KL1 KL2 KL1 = Kolumbo Line KL2 = Kameni Line NC = Northern Caldera SC = Southern Caldera Christiana Ridge (CR) NC SC Kolumbo Any dro s F au lt (A F) Christiana fault 148 105 a) b) Cretan Basin x y Figure 2.2. The Santorini region showing the PROTEUS active seismic experiment and the main morphotectonic features. (a) Topographic/bathymetric map of Santorini and the surrounding islands showing seafloor and island seismic stations (yellow circles are stations used in inversion, grey circles are stations that were not used) and the seismic shot profiles (small red circles). Data from seismic lines recorded on stations 148 and 105 (blue/purple) are shown in Figure 2.3. (b) Topographic/bathymetric map with the main basins, horsts/ridges, and faults (red lines, from Hooft et al., 2017). Abreviations used are: CB-Christiana Basin, CR - Christiana Ridge, IF - Ios Fault, Anydros Horst, AB - Anydros Basin, AFB -Anafi Basin, SAB - Santorini-Anafi Basin, AAB - Amorgos-Anafi Basin. Kolumbo and Kameni lines (KL1 and KL2, respectively) are after Pfeiffer (2001). 10 2.2.2 Volcanic Background Regional volcanism has been localized in three areas: Christiana Island, Santorini volcano and the Kolumbo volcanic chain, arranged roughly in a NE-SW direction (Nomikou et al., 2013) (Figure 2.2). The oldest of the regional volcanic deposits results from Christiana volcanism (active during late Pliocene) and from early volcanic centers at the SW edge of Santorini near Akrotiri (~0.6 Ma) (Piper et al., 2007). Volcanism at Santorini itself began roughly 650 ka (Druitt et al., 1999), with explosive volcanism beginning around 360 ka. At least 4 major caldera- forming eruptions have occurred at Santorini (Druitt, 2014), the most recent of which, the 30-86 km3 (dense rock equivalent) Late Bronze Age (LBA) "Minoan" eruption, occurred 3.4 ka (Druitt, 2014 and citations therein; Johnston et al., 2014; Friedrich et al., 2006). Post-LBA effusive eruptive vents are located along the Kameni line, a NE- SW-trending line of vents in the caldera (Nomikou et al., 2014; Pyle & Elliott, 2006) that results from either a deep seated fault focusing magmatism, a caldera ring fault, or a region of diking (Konstantinou et al., 2013; Newman et al., 2012; Papadimitriou et al., 2015; Saltogianni et al., 2014; Tassi et al., 2013). The Kolumbo line, a similarly oriented lineament north of the Kameni line (see Figure 2.2), is observed as a linear alignment of older volcanic centers in the NE caldera and is thought to strike toward the Kolumbo volcanic chain NE of Santorini. The Kolumbo volcanic chain is a NE-striking alignment of submarine seamounts (e.g., Hooft et al., 2017; Nomikou et al., 2012; 2013), the largest of which is Kolumbo Seamount (Hübscher et al., 2015; Nomikou et al., 2016). The interaction between magmatism at Santorini and Kolumbo is still debated. Petrologic studies indicate that their respective crustal magmatic systems are not linked (Klaver et al., 2016), though earthquake tomography suggests a 11 possible connection below 5 km depth (Dimitriadis et al., 2010). The NE-SW strike of regional volcanism, combined with NE-SW striking fault zones, has led other researchers to suggest an interaction between magmatism and tectonic stresses (e.g., Dimitriadis et al., 2009; Feuillet, 2013). Similar NE-SW trending faults are also present at other large Aegean volcanoes (Papazachos & Panagiotopoulos, 1993; Nomikou & Papanikolaou, 2011). 2.3 Experiment Geometry and Data Acquisition 2.3.1 Seismic experiment In November and December of 2015, a three-dimensional, active-source seismic tomography experiment was conducted in the broader Santorini volcano area of the southern Aegean Sea. The experiment covered an area roughly 120 km x 45 km centered on Santorini, with the goal of imaging the crustal magmatic plumbing system beneath the volcano (Figure 2.2). Data were collected on 91 ocean bottom seismometers (OBSs) and 65 land seismometers distributed around Santorini’s caldera, as well as on Anafi, Christiana, and Anydros islands. The OBSs included 30 Woods Hole Oceanographic Institution (WHOI) instruments (4.5 Hz Geospace 3-axis geophone) and 61 Scripps Institute of Oceanography (SIO) instruments (4.5 Hz Sercel L-28 3-component geophone). Both OBS types also had a High Tech HTI-90-U hydrophone. The land seismometers included 60 Mark 1-Hz geophones from the German Research Center for Geosciences Geophysical Instrument Pool in Potsdam and 5 CMG-40T and Trillium compact (120s) seismometers from the Aristotle University of Thessaloniki. All OBS instruments had a 200-Hz sampling rate and all land stations used a 100-Hz sampling rate. There were over 14,300 active-source marine shots using a 6600 in3 36-component airgun array towed at 12 m depth. Average shot spacing was ~150 m along ENE- 12 WSW-oriented shot lines spaced at 1-2 km intervals and included shot-receiver offsets up to ~115 km. Additional azimuthal coverage was achieved using a lower shot-density NW of Santorini and stations located on the neighboring Anafi island (Figure 2.2a). 2.3.2 Data return and data quality The OBS data return was sufficient with 1 OBS lost and an additional 10 OBSs with noisy and/or poor-quality records on both the hydrophone and vertical channels. A sporadic ~6 Hz ringing noise was observed on several SIO stations that did not correlate to any external processes such as wind, lightning, boat traffic, etc. This noise was of variable amplitude and occurred randomly on all 4 channels. Figure 2.3 provides an example of good quality OBS data for two stations located in the Christiana and Anydros basins. Differences between the basins are clearly observed, with large, rather impulsive first arrivals with short coda in the Christiana basin and more chaotic arrivals with a "ringy" character and longer coda in the Anydros basin. Santorini land stations had variable quality data. Those located on metamorphic rocks and exposed bedrock had great return; in contrast those situated on volcanic deposits were noisy and difficult to pick. Clear impulsive arrivals were seen on Anafi stations, as all these stations were installed on metamorphic basement, providing good longer-range azimuthal coverage to the experiment. However, the Anafi stations were located outside the velocity model used in this paper and thus picks for these stations were not included. For upper crustal Pg waves crossing the caldera area, arrivals were highly attenuated and travel times for these stations were difficult to pick due to emergent waveforms (Figure A.1). For seismic waveforms that did not travel within the 13 0 10 20 30 40 3 2 1 0 0 10 20 30 40 3 2 1 0 tim e - x /6 (s ) x-distance (km) 3 km 10 k m 20 k m 10 k m 20 k m 5 km 10 k m 15 k m 20 k m 25 k m 5 km 10 k m 15 k m W E W E Christiana Basin Anydros Basin Station 148: Hydrophone Station 105: Hydrophone Range (km) a) b) tim e - x /6 (s ) Figure 2.3. Seismic data recorded in basins east and west of Santorini. Seismic record sections (hydrophone) for shot lines in the Christiana (top) and the Anydros Basins (bottom) shown with a reduction velocity of 6 km/s. Shots in the Christiana Basin are characterized by a large impulsive first motion in contrast to the more ’ringy’ character of those in the Anydros Basin. There is good agreement between travel time picks (red) and predicted travel times through our preferred model (blue). Regions shaded grey correspond to near shot ranges (0-6 km) which were excluded from the inversion (see text for details). footprint of the volcano, clear, impulsive arrivals were observed, indicating that any attenuative structure was located beneath the caldera. 2.4 Data processing and tomographic inversion 2.4.1 OBS relocation The OBSs were relocated on the seafloor by minimizing the misfit between predicted and observed acoustic water-wave arrival times (Creager & Dorman, 1982) for short range arrivals (0-2 km) (longer ranges were included when 14 necessary). A constant water velocity of 1.52 km/s (determined from expendable bathythermographs) was used and a pick error of 5 ms was estimated. Station locations were fixed to the seafloor using the bathymetric map from Hooft et al. (2017). OBS depths ranged from ~30 m to ~890 m, with typical depth uncertainties of 10 m and horizontal uncertainties less than 4 m. Using the precision of the water-wave arrivals (most stations were fit to water-wave travel-time RMS values of ~5 ms), we were able to identify and correct several errors in the dataset including origin time offsets and mis-located shots. In addition, a non-linear response at short ranges (typically < 0.8 km) was observed on the hydrophone for many instruments, especially shallow stations. This effect did not influence picking of the first motion of water-waves, although it did affect the resulting waveform shape (Figure A.2). Finally, we were able to identify and correct for a linear drift in the OBS clock for one instrument that had not been accounted for in the initial data processing. 2.4.2 Pg travel time data We picked over 200,000 Pg first arrivals using two approaches. Initial picking was conducted using an autopicker from the open-source opendTect software (https://www.dgbes.com/). Several tens of thousands of arrivals with high signal to noise ratio (SNR) traces (e.g. short ranges, predominately less than 20 km range) were collected using this approach. The picking error for these arrivals was assigned a value of 10 ms, following visual inspection of the automatic picks. After this first step, arrivals were picked manually. Errors were visually assigned during the picking process and ranged from 5 ms (high SNR, exceptional quality data) to 30 ms (low SNR); the median error was 10 ms with standard deviation of 13 ms. The difference in assigned errors resulted from both variability in the noise level, as well as differences in waveform shape and arrival time due to surface and subsurface 15 complexity. Data were picked on the hydrophone, vertical, and/or a scaled linear stack of the hydrophone and vertical channels. All picks (manual and automatic) were made on the first negative to positive zero crossing (using the polarity convention of the hydrophone channel, Figure 2.3) as it is the easiest portion of the first arrival pulse to pick. This zero-crossing followed a small negative first motion that was only easily observed in the highest quality data. All picks were made on waveforms filtered with a 4th order causal Butterworth filter of 5-25 Hz, for shots with distance ranges between 0 and 65 km. Picking resulted in a high- quality dataset for distances between 4 and 30 km at most stations. 2.4.3 Tomographic Inversion We inverted the Pg travel time first arrivals using the approach of Toomey et al. (1994), minimizing the squared residual between observed and predicted travel times while also penalizing against both the magnitude and roughness of model perturbations (roughness measured using Laplacian smoothing). The slowness model was defined on a 120 km x 45 km x 12 km (x, y, and z dimensions) rotated rectangular grid for the forward problem, with a grid spacing of 200 m for both horizontal (x and y) and vertical (z) dimensions, and bathymetry reflected by vertical shearing of the grid (Toomey et al., 1994). The grid was rotated 25.5o counter-clockwise from north, to align the x-axis with the shot-line orientation (Figure 2.2a). Travel times through the crust were calculated using the graph theory approach of Moser (1991), with the water-wave segment of the travel-time (shot to seafloor) calculated on a grid with a 50 m x 50 m horizontal spacing, using a constant water-wave velocity of 1.52 km/s. For the linearized model inversion, a perturbational grid of 400 m x 400 m x 200 m in the horizontal and vertical directions, respectively, was used, inverting for slowness perturbations. Updated 16 slowness values were then linearly interpolated onto the forward problem grid. Iterating on this linearized inversion strategy allowed for an accurate approximation to the non-linear travel time tomographic problem (see Toomey et al., 1994 for additional details) A number of inversions were conducted to create a smooth 3-D VP starting model, so that large velocity contrasts resulting from the metamorphic horsts and sediment-filled grabens were included in the starting model. To first obtain the best 1D velocity model for the region (Figure 2.4), a 3D inversion was conducted using a 1-D VP starting model derived from a combination of prior gravity, seismic refraction, and receiver function studies (Bohnhoff et al., 2006) (blue line in Figure A.3). The 3-D output velocity model was averaged at each depth and the new 1-D model was used as an updated starting model. This process was repeated and allowed for the migration to an optimized regional 1-D velocity model (black line Figures 2.4 and A.3). To obtain the smooth 3-D VP starting model, we used this regional 1-D velocity model and inverted for 3-D isotropic velocity variations, which were then spatially smoothed with a median filter of 5 km by 5 km by 2 km in the horizontal (x and y) and vertical (z) directions, respectively. For the final inversion we used horizontal and vertical smoothing parameters of 200 and 100, respectively, and penalized model perturbations relative to the previous model iteration using a penalty of 1 (see Toomey et al., 1994 for more detail). Each inversion consisted of 5 model iterations, ensuring the convergence of the RMS travel time misfit (Figure A.4). We conducted tens of trial inversions and the main model features presented in this paper were insensitive to reasonable variations of the inversion parameters (Table A.1, Figures A.4 & A.5). Ranges shorter than 6 km were poorly fit in the initial inversions, a result of the lack of short-range travel-time picks and a large grid spacing (200 x 200 x 200 m) relative to the ranges. Picks associated with these ranges were therefore 17 1 2 3 4 5 6 7 Velocity (km/s) 0 1 2 3 4 D ep th (k m ) 10% 0% 5% Intrusions and metamorphics Probability Figure 2.4. 1-D P-wave velocity-depth profiles. Averaged 1-D velocity depth profile of four selected areas around Santorini (outlined in subfigure), compared to the average regional velocity profile (black line). Basin fill is assumed for velocities less than 4 km/s and metamorphic rocks and intrusives for velocities faster than 4 km/s - this corresponds to a steep gradient in the velocity-depth curve. The light blue curve highlights the P-wave velocity for the Anydros metamorphic horst (Fig. 2.2), showing faster than average velocities of the metamorphic rocks at shallow depths (0-2 km). At > 2 km depth, areas on the western side of Santorini (red and magenta) are systematically faster than those on the eastern side (dark blue and light blue). Background grey-scale shows the probability density function distribution of all 1-D velocities of the tomography model. removed from the inversions. The model presented here (Figure 2.5) was fit to an RMS travel-time misfit of 15 msec, which corresponds to a χ2 of 2.2. To ensure the accurate recovery of structures, initial inversions only used the higher quality, often shorter-range data (< 15 km). By predicting expected (theoretical) arrival times through this initial tomographic model, we were able to identify mis-picked arrivals and facilitate the manual picking of noisy first arrivals, which were skipped in the initial picking effort. Using this approach, we extended the picked dataset from < 15 km (high signal-to-noise) to > 30 km (often lower signal-to-noise). 18 b) 2 km c) AH CR CB AB AFB IF SAB AAB 10 km 0 km a) AH CR CB AB AFB IF SAB AAB 10 km 3 km d) AH CR CB AB AFB IF SAB AAB 10 km 1 km 10 km AH CR CB AB AFB IF SAB AAB b) dv km/s Figure 2.5. Velocity anomalies relative to the 1-D average velocity-depth profile at 0, 1, 2, and 3 km depth. Background is illuminated bathymetric map from Hooft et al. (2017). Grey lines are faults defined using the seismic tomography images. These faults are colored black on the depth slice on which they were defined. Dashed black lines are large faults outside the region of resolution. Abbreviations as in Figure 2.2b. 2.5 Results and Interpretation 2.5.1 Upper crustal velocity variations The tomographic model shows substantial P-wave velocity variations in the upper crust of the study area, with lateral differences in velocity exceeding 3 km/s near the surface (Figure 2.5). In the top-most kilometer, regions of anomalously high (+1.5 km/s) and low (-1.5 km/s) relative velocity correspond to mapped metamorphic basement and sedimentary basins, respectively (Figures 2.2 & 2.5a- b). At depths greater than 2 km, the velocity west of Santorini is higher and 19 spatially more uniform compared to the eastern side of the Santorini volcano, where velocities are both lower and more variable (Figures 2.4 & 2.5b). At 3 km depth, the overall lateral velocity variability across the study area is still ~2 km/s (± 1 km/s) (Figure 2.5d). The reliability of the recovered longer wavelength lateral velocity variations is validated by checkerboard resolution tests (Text A.1, Figures A.6, A.7 & A.8), which show that features with length scales of 5 km and greater are well recovered throughout the model, while features with length scales of 3 km are well recovered within the higher-velocity areas, mainly metamorphic basement. Rapid velocity changes between the low-velocity sedimentary basins and higher velocity metamorphic basement rocks are interpreted as faults. Near- surface faulting, delineated by sharp velocity changes observed in the 0- and 1-km- depth slices (heavy black lines in Figure 2.5a&b) is in good agreement with faults observed in the topographic-bathymetric map (Figure 2.2). At the depth of 2 and 3 km, we interpret similar sharp spatial velocity gradients as faults within or beneath the basins (heavy black lines in Figure 2.5c-d). 2.5.2 Comparison of tomographic velocity model with seismic reflection images In general, first order geotectonic features, such as large-scale sedimentary basins and their bounding faults, are well resolved in both tomographic and prior seismic reflection datasets and show similar geometries and structures. Figure 2.6 shows the location of 7 cross-sections where detailed model evaluation and interpretation were performed, of which profiles A-A’, B-B’ and C-C’ have associated seismic reflection results (Figure 2.7). Figure 2.7a compares the seismic tomography cross-section to a multi- channel seismic (MCS) profile that crosses the Anydros Basin, Anydros Horst, and Anafi-Amorgos Basin from NW to SE (Nomikou et al., 2018) (Figure 2.6). 20 D D’ E E’ F F’ G G’ A A’ B B’ C C’ Figure 2.6. Map showing the location of seismic cross-sections. A-A’, B-B’ and C- C’ (purple lines) indicate the locations of the three seismic reflection profiles (from prior studies) and corresponding velocity cross-sections (this study) that are shown in Figure 2.7. D-D’, E-E’, F-F’ and G-G’ (red lines) show the locations of the four interpreted tomography cross-sections through regional basins shown in Figure 2.9. Tomographically defined faults (black lines) are after Figure 2.5. Orange regions mark areas of diffuse micro-seismicity (Bohnhoff et al., 2006; Brüstle et al, 2014). The transition across a large-offset normal fault into the Anafi-Amorgos basin accurately coincides with an abrupt change from high to low velocities in the tomographic image. A smaller basin bounded by secondary faults is similarly expressed tomographically in the Anydros Horst footwall. The transition from sediment to the underlying basement of the Anafi-Amorgos basin corresponds approximately to the 4 km/s velocity contour. Additional comparisons with the MCS results (Nomikou et al., 2016) in the vicinity of Kolumbo submarine volcano are presented in Figures A.9 and A.10. A seismic tomography comparison to a W-to-E seismic reflection profile within the Christiana Basin (Tsampouraki-Kraounaki & Sakellariou 2018) is presented in Figure 2.7b. In the reflection image, the basin is filled by sediments (Units 1 -5, Figure 2.7b) intercalated with pyroclastic flows (Roman numerals), 21 with Unit 6 proposed to be Messinian evaporites, a late Miocene marker (Tsampouraki-Kraounaki & Sakellariou 2018). In the center of our tomographic velocity profile, elevated seismic velocities relative to the surrounding sediments (3 - 4 km/s versus 1.5 - 3 km/s) correlate with an updoming of the Messinian evaporites, an observation consistent with research showing that evaporites are seismically faster than sediments and pyrolastic flows (e.g., Zong et al., 2017). Small-offset faults within the sediments on the eastern end of the reflection profile correlate with underlying variations in basement structure in the tomography images. Figure 2.7c shows a S-N seismic reflection profile through the Christiana Basin (Tsampouraki-Kraounaki & Sakellariou 2018) and its comparison with tomographic results. Generally, the main basin is seismically slow, whereas the basement rock (Unit 7 in top figure) is seismically fast (~3.5 to 5.5 km/s). In the northern portion of the basin the dip of the margin is well recovered. An old buried basin margin on the southern edge of the Christiana basin, thought to have become inactive ~1 Ma (Tsampouraki-Kraounaki et al. 2018), is also tomographically identified as seismically faster than the main portion of the basin. Near-vertical faults observed in the reflection images (red lines) appear to spatially correlate with variations in the underlying basement, similar to Figure 2.7b. These faults have been proposed to be strike-slip features associated with a prior episode of deformation, which ceased activity ~1 Ma, as evidenced by the undisturbed sediments overlying the faults (Tsampouraki-Kraounaki et al. 2018). While the travel time tomographic velocity model is less detailed than the seismic reflection images with respect to structure and deposition sequence, it provides valuable velocity and depth constraints, as well as fuller three-dimensional spatial coverage than the existing reflection imaging. The tomographic images also 22 0 -1 -2 -3 0 5 10 15 20 25 30 vertical exaggeration 4:1 Distance (km) tomography - depth (km) old margin 0.6 1.5 0 30 B B’ Updoming of Messinian Evaporites0 30 MCS - TWTT 0.6 1.5 0 30 -3.5 vertically exaggerated 4:1 Distance (km) tomography - depth (km) Christiana Basin 0.5 0 1 2 0 10 20 30 TW TT (s ) A A’ MCS - TWTT 0 1 2 0 10 20 30 TW TT (s ) MCS and tomography - TWTTsecondary faults MCS and tomography - TWTT 0 10 20 30 0 -1 -2 -3 El ev at io n (k m ) tomography - depth (km)vertically exaggerated 4:1 AAB Distance (km) AH 0.5 1 1.5 old margin 0 30 0.5 1 1.5 C C’ 0 30 a) b) c) Vp (km/s) Figure 2.7. Comparisons of tomography velocity model with seismic reflection profiles. Upper panels depict seismic reflection profiles from previous studies (locations shown in Figure 2.6). Middle panels show seismic velocity from this study overlain on the seismic reflection image, after converting depth into a Two- Way Travel Time (TWTT). Bottom panel is the same seismic velocity cross-section shown as a function of depth. (a) Seismic reflection profile (H14) from Figure 6 of Nomikou et al. (2018) across the Anydros Ridge showing tomographic recovery of the Anafi-Amorgos Basin (AAB) as well as recovery of secondary faulting on the Anydros Horst (AH) (b) E-W seismic reflection profile across the east-central Christiana basin (Figure 7 of Tsampouraki-Kraounaki & Sakellariou 2018) showing the correlation between the seismic velocity structure and faults in the seismic reflection data. The authors interpret Unit 6 as Messinian evaporites and the region of up-doming of this layer correlates with higher seismic velocities. Red lines in bottom panel are faults from the seismic reflection data. (c) S-N seismic reflection profile across the eastern portion of the Christiana basin (Figure 5 of Tsampouraki- Kraounaki & Sakellariou 2018) showing thin sediments over an old basin margin. Shallow faults from seismic reflection studies (red lines) correlate well with deeper undulations of basement structure. reveal deeper features such as faults that ultimately control the shallower structures observed in the seismic reflection images. 2.5.3 Mapping geometry and thickness of sedimentary basins from the tomography model We outline basin depth using a velocity of 4 km/s throughout the model and map both the two-way travel-time (TWTT) and the depth to the 4 km/s 23 iso-velocity contour (Figure 2.8). Visual comparison between seismic reflection images and tomography results indicates that this value typically corresponds to the sediment-basement interface (e.g. Figure 2.7 & A.11). The 4 km/s velocity also corresponds to the midpoint of a rapid increase in average seismic velocity with depth (Figure 2.4), interpreted as the transition from seismically slow sediments to the underlying, seismically fast metamorphic basement rocks. We contour the depth to the 4 km/s iso-velocity to delineate the 3D geometry and thickness of the sedimentary basins across the entire study area (Figure 2.8a), and not just the profiles that were mapped using TWTT from seismic reflection studies (e.g. Nomikou et al., 2016). Figure 2.8 shows how the faults identified in Figure 2.5 correlate with, and control, the geometry and internal structure of the basins. Cross-sections through the tomography results on two SW-NE cross-sections through the Christiana Basin west of Santorini and two WNW-ESE cross-sections through the Anydros and Anafi Basins east of Santorini are shown in Figure 2.9 (with locations of the profiles in Figure 2.6). This figure validates and elucidates the faults identified in the map views (Figure 2.5) and their relationship to basin structure (Figure 2.8). 2.5.4 Western side of Santorini: Christiana Basin and Christiana Ridge The anomalously low P-wave velocities at 0-2 km depth in the western part of the model coincide with the NW-SE striking Christiana Basin (Figures 2.2 & 2.5). Low-velocity anomalies associated with the basin extend to ~1 km depth in the basin center and down to 2 km in its SE and NW parts, indicating the presence of two deeper sub-basins (Figure 2.5 and 2.9). The SE sub-basin is deepest close to Santorini, near Christiana island (Figure 2.5d). Results from previous seismic reflection studies suggest that these sub-basins formed in the Early to Middle 24 CB AFB SAB AAB AB SE sub-basin NW sub-basin thin cover of sediments th in co ve r o f s ed im en ts thin cover of sediments TWTT thickness (s) a) b) CB AB AFB SAB AAB Thickness (km) Figure 2.8. Sedimentary basin thickness maps from the seismic tomography model. (a) Basin thickness, determined using the 4 km/s velocity contour as the sediment-basement transition, with relevant geological features labeled. (b) Tomographic basin thickness converted to TWTT for comparison with seismic reflection studies. The Anydros basin, despite being a prominent tectonic feature on bathymetric maps, has relatively shallow sediment fill (1-1.5 km). In contrast, the Amorgos-Anafi Basin and the Santorini-Anafi basins as well as the relatively inactive Christiana basin contain thick sediment fill (>2 km). Faults after Figure 2.5, with deeper faults (2-3 km depth) shown in light grey and shallower faults (0-1 km) in dark grey. Dark shading indicates areas with poor resolution of sediment thickness. Labels as in Figure 2.2. 25 Christiana Basin Christiana Basin v (km/s)dv (km/s) vertical exaggeration 2:1 D D’ E E’ old margin bathymetric margin bathymetric margin old margin Christiana BasinCR CR Christiana Basin Christiana Basin E E’ buried block D D’ CR Christiana Basin CR El ev at io n (k m ) old margin bathymetric margin bathymetric margin old margin SW facing normal fault SW facing normal fault Distance (km) Anydros Basin F F’ G G’Anydros Horst Distance (km) Anydros Basin F F’ G G’Anydros Horst buried ridge buried ridge a) b) Figure 2.9. Seismic velocity cross-sections through the Christiana and Anydros basins. (a) Profiles D-D’ and E-E’ through the Christiana basin in velocity (v) and velocity anomalies (dv) with interpretations of main fault geometries shown in black on dv cross-sections. The open triangles mark where the profiles cross the black faults shown on Figure 2.6. These profiles show evidence for down-dropped blocks within the Christiana basin. (b) Profiles F-F’ and G-G’ through the Anydros and Anafi basins, following conventions described above. These two basins show thinner sedimentary fill than the Christiana basin, more pervasive faults at depth, and are regionally characterized by a seismically slower basement velocities than the profiles through the Christiana basin (D-D’ and E-E’) (see also Figure 2.4). Pleistocene, before continued expansion was accommodated by wider faults in the north and south (Tsampouraki-Kraounaki & Sakellariou 2018). The Christiana basin is separated from the Sea of Crete to the south by the Christiana ridge (Tsampouraki-Kraounaki & Sakellariou 2018) (Figures 2.2 & 2.5). The northern, bathymetrically expressed margin of the ridge proper (dashed black line north of CR in Figures 2.5a and 2.5b) has little tomographic expression, showing a minor velocity contrast across the fault (Figure 2.9a). The tomographically expressed fault margin (solid black line above CR in Figure 2.5b) is located basin-ward (north) of the ridge proper, striking NW-SE, and reflecting the presence of an old basin margin, buried under a thin veneer of sediments 26 (Tsampouraki-Kraounaki & Sakellariou 2018, see also Figure 2.7c). This fault, which dips at an angle of 25-40o, marks the deepening of the basin to km-scale depths (Tsampouraki-Karounaki et al., 2018) (Figures 2.8 & 2.9a). The northern margin of the Christiana basin is marked by a large SW-facing normal fault. While this fault is clearly evident in Figures 2.8 & 2.9a, it has little bathymetric expression close to Santorini (Figure 2.2), most likely because it is covered by volcanic deposits. On the contrary, in the western part of the model away from Santorini, it is identified in both the tomography model and the seafloor bathymetry as seen in the D-D’ and E-E’ model cross-sections and their proposed interpretation (Figure 2.9a). At ~2 km depth, and basin-ward of the northern basin-bounding fault, there is a large buried normal-fault block, dipping to the SSW at an angle of 25-40o (solid black line north of CB in Figure 2.5 and solid black line labelled buried block in Figure 2.9a). This fault forms the northern margin of the SE sub-basin. 2.5.5 Eastern side of Santorini: Anydros Basin, Anafi Basin and Anydros Horst The two large NE-SW trending basins on the eastern side of Santorini, the Anydros (AB) and Anafi (AFB) basins, are tomographically identified at 0-1 km depths as seismically slow regions (Figures 2.5a and b and Figure 2.9b). The Pliocene/Quaternary-aged Anydros Basin has thin basin fill and appears to be only ~1.5 km thick (Figures 2.8 & 2.9b). The similarly aged Anafi basin is divided into two sub-basins by a buried ridge at <1 km depth (Figure 2.5), the Anafi-Amorgos basin (AAB) to the north and the Santorini-Anafi basin (SAB) to the south. Both sub-basins are up to 2 km thick. The buried ridge dividing these sub-basins has an ENE-WSW orientation (Figure 2.5b). 27 On the eastern side of Santorini, we observe tomographically resolved variations in the strike of basin margins of up to 20o from a mean NE-SW direction. For example, the northern margin of the Anydros basin, the Ios fault (IF in Figure 2.5), strikes approximately N40oE, whereas the southern margin of the Anydros basin strikes roughly N25oE. Similarly, the large dipping fault on the northern margin of the Anafi-Amorgos basin (the Santorini-Amorgos fault) is curved and has strikes ranging from N25oE to N60oE (Figure 2.5), a pattern consistent with sea-floor morphology (e.g. Hooft et al., 2017, Nomikou et al., 2018) (Figure 2.2b). The Anydros and Anafi basins are separated by the Anydros Horst (AH), which has typical bedrock velocities of 5-6 km/s at shallow depths (<1 km), in contrast to the low velocities in the basins (2-4 km/s) (Figure 2.9b). Close to Santorini, this horst is buried under a thin cover of sediments, possibly by volcanic eruption deposits, as suggested by the presence of a relatively flat bathymetry but a strong high-velocity tomographic signature. 2.5.6 Structures associated with Santorini Several NE-SW striking faults extend from the western side of the study area (e.g. Christiana basin region), through Santorini, to the eastern side (Anydros Horst and Anafi basin region). At shallow depths, metamorphic blocks that are part of the pre-existing volcanic basement and that outcrop in southern Santorini are well recovered as seismically fast regions (Figures 2.5a and 2.10). The NE-SW striking Akrotiri fault on the western side of Santorini, which is identified in the bathymetry south of Santorini (Figure 2.2) (Hooft et al., 2017), is tomographically observed at 0-1 km depth as a prominent velocity contrast that strikes through Santorini and out to the east toward the Anydros Horst region (Figure 2.5a-b) 28 juxtaposing the seismically slow basin sediments of the Anydros Basin to the north against the seismically fast metamorphic basement to the south. This fault, which extends from the southwestern termination of the Christiana basin, through Santorini, to the margin of the Anydros Horst on the east, is subparallel to the regional alignment of volcanic centers (Figures 2.5a and 2.5b). At deeper depths (2-3 km), a tomographically defined fault strikes through the northern caldera basin, passing through NE Santorini. This fault may also be connected to a bathymetrically expressed fault extending NE from Christiana island (Figure 2.2b). From Santorini’s northern caldera, the fault extends northeast toward Kolumbo volcano (Figures 2.5c & A.10). At 1-2 km depth a large circular, low-velocity anomaly is observed in the center of the northern caldera basin, which has been proposed to be related to caldera collapse (Hooft et al., 2019) (Figure 2.10). This anomaly directly overlies the inflation source from a 2011-2012 unrest period (inferred source depth of ~4 km) (Parks et al., 2015) and is bounded by the two dominant tectono-magmatic lines on Santorini, the Kameni and Kolumbo lines (Pfeiffer, 2001). The southern margin of the anomaly marks the location of recent volcanism (Kameni lavas, Figure 2.10) (Pyle and Elliott, 2006). Its shape matches that of the shallow basin- fill of about 100 m thick, observed in previous seismic reflection images and inferred to correspond to LBA eruption deposits (Johnson et al., 2015). 2.6 Discussion 2.6.1 Differences between the east and west sides of Santorini and relationship to faulting The area east of Santorini is seismically active and exhibits ongoing, distributed faulting including a MS = 7.4 normal-faulting event on the Santorini- 29 dv (km/s) 5 km volcano-tectonic lines 3 km depth approximate dike orientation exposed dikes Kolumbo line (this study) N Exposed dike (Therasia) local fault Exposed dike orientations N Exposed dike (Therasia) Exposed dike orientations Kolumbo Kameni Lavas Therasia Lavas Skaros Lavas Peristeria Volcanics Akrotiri Volcanics Pre-volcanic basement Kameni line? (this study) 1 km depth 5 km 5 km a) b) c) Figure 2.10. Comparison of the seismic velocity beneath Santorini with volcanic features and exposed geology. (a) Geologic map of Santorini (modified from Druitt et al., 2016) with dike locations and orientations (Browning et al., 2015; Fabbro et al., 2013), the Kolumbo and Kameni tectono-magmatic lineaments (defined by prior studies), locations of small-scale faulting (Druitt et al., 1999), location of the 2011-2012 inflation source (Parks et al., 2015), long wavelength gravity data (black contours at 2 mGal intervals; Budetta et al., 1984), and a LBA (Late Bronze Age) deposit thickness map from seismic reflection data (modified from Johnston et al., 2015). (b) Comparison of previously proposed tectono-magmatic lineament locations (red lines), 2011-2012 inflation point source (blue dot), and Late Bronze Age (LBA) deposit thickness (modified from Johnston et al., 2015) with relative velocity (dv) at 1 km depth. An increase in the LBA deposit thickness directly overlies a decrease in velocity associated with caldera collapse (Hooft et al., 2019) and also overlies the 2011-2012 inflation point source at ~4 km depth (Parks et al., 2015). (c) Comparison of locations of exposed dikes, their orientations, faults, and long wavelength gravity with dv at 3 km depth. The Kolumbo line (labelled) is clearly observed in the tomography, dividing slower seismic velocities to the SE from faster velocities to the NW. The orientation of the NE-SW striking line parallels exposed dike orientations and matches the strike of regional faults. The Kameni line (labelled) is also observed in the tomography, paralleling the Kolumbo line. 30 Amorgos fault in 1956 (Brüstle et al., 2014; Konstantinou, 2010; Okal et al., 2009; Papadopoulos & Pavlides, 1992). There are also two regions of small earthquakes: those around Kolumbo that are thought to result from magmatic processes (Bohnhoff et al., 2006; Dimitriadis et al., 2009) and clustered earthquakes around the Anydros Horst (AH) that may reflect upward migration of fluids within a zone of tectonic weakness or the development of volcanic activity (Bohnhoff et al., 2006) (e.g. Figure 2.6). In contrast, the west side is characterized by the seismically quiet, older Pliocene faulting of the Christiana Basin (e.g. Bohnhoff et al., 2006). These differences have led to the interpretation that the AH is part of a boundary that accommodates the relative motion between a competent Cycladic block and a less-competent eastern Aegean region, dividing the Aegean into a seismically quiet west and more active east (e.g., Bohnhoff et al., 2006; McClusky et al., 2000; Reilinger et al., 2010). At ~3 km depth the basement east of Santorini has a lower average seismic velocity than to the west of Santorini by ~0.4 km/s (7%) (Figures 2.4 and 2.5), which can be attributed to the presence of dense, distributed faulting in AH region, reducing rock competency. Preliminary plots of travel time misfit as a function of azimuth show NE-SW-oriented seismic anisotropy which results from a fracture network in this region (Figure A.12). Focal mechanisms of shallow earthquakes from the AH area (Friederich et al., 2014; Dimitriadis et al. 2009) are also consistent with normal faulting due to NW-SE 130-155o extension, indicating ongoing NE-SW fault activity in this region. An alternative explanation for the difference in average velocity on the east and west sides of Santorini is that it is generated by differences in composition. While the presence of carbonates, flyschs, greenschists, blueschists, and granites (Kilias et al., 2013) indicates that variable seismic velocities due to compositional 31 differences should exist, the orientation of the geological units is mainly controlled by N-S-dipping regional detachments, which is unlikely to produce significant NE- SW velocity variations. We conclude that the association of the lower P-wave velocities east of Santorini with active deformation and pervasive fracturing of the basement is the most plausible scenario. 2.6.2 Tectonic evolution of the basins and Christiana-Santorini-Kolumbo magmatism: Localization of magma in a proto-Anydros Basin Using the delineated faults and basin structures, we refine an existing model for the tectonic evolution of the Santorini region from the Miocene-Pliocene to present (Piper et al., 2007) and investigate how tectonism interacts with, and localizes, magmatism (Figure 2.11). While the tomographic velocity images provide information on the strike and style of faults, absolute time constraints on fault activity rely on other studies, mainly seismic reflection imaging. The earliest stage of faulting in the region, during the Miocene-Pliocene (Figure 2.11a), resulted in WNW-ESE-oriented faults that define the Christiana Basin and likely the buried ENE-WSW faults that divide the Anafi basin (Anastakis and Piper, 2005; Piper et al., 2007) (hereafter these faults will be referred to as E-W to be consistent with the literature). The offset between these two sets of tomographically resolved faults (Figures 2.5 and 2.11a) supports the inference of Piper et al., (2007) that a transfer zone may have existed striking approximately N through the area where Santorini currently resides. In the late Pliocene to Pleistocene (Figure 2.11b), these predominately E-W structures were cross-cut by NE-SW striking faults (Piper et al., 2007). This may have occurred as a result of NW-SE extension due to differences in motion between the Cycladic and eastern Aegean blocks (e.g. Reilinger et al., 32 24˚45' 25˚00' 25˚15' 25˚30' 25˚45' 26˚00' 36˚15' 36˚30' 36˚45' 24˚45' 25˚00' 25˚15' 25˚30' 25˚45' 26˚00' 36˚15' 36˚30' 36˚45' 24˚45' 25˚00' 25˚15' 25˚30' 25˚45' 26˚00' 36˚15' 36˚30' 36˚45' 24˚45' 25˚00' 25˚15' 25˚30' 25˚45' 26˚00' 36˚15' 36˚30' 36˚45' Pliocene Pliocene Pleistocene Pleistocene Present Cycladic Block Eastern Aegean Block transfer zone (?) a) b) c) d) Pro to -A nyd ro s B as in Christiana Volcanism Akrotiri Volcanism Kolumbo Volcanism bathymetric margin buried margin buried block Figure 2.11. Fault evolution and its relationship to magmatism: Sketch of the evolution of faulting and volcanism in the Santorini area using the faults defined from the tomographic model (Figure 2.5) and building on the tectonic evolution model of Piper et al. (2007). Temporal constraints are taken from previous studies (Piper et al., 2007). Red lines and red shading show active faults during each time period, hatched areas indicate basins, red circles indicate regions of volcanic activity, black arrows indicate approximate extension direction for each period. (a) Formation of the Christiana Basin as a full-graben structure in the Pliocene under NNE-SSW extension. (b) Transition to NW-SE extension leading to Anydros Horst formation from the Pliocene-Pleistocene on, with initial formation of a proto-Anydros Basin. (c) Initiation of Christiana volcanism in the Pleistocene. (d) Volcanism at Santorini and Kolumbo developed in the Quaternary within the proto-Anydros Basin. Current diffuse seismicity (orange region; Bohnhoff et al., 2006, Brüstle et al, 2014) occurs predominately on the eastern side of Santorini. 2010). These faults formed primarily on the eastern side of Santorini (Figures 2.5, 2.11b) and the earlier E-W fault systems became mostly inactive (e.g. Piper et al., 2007). The tomographic results indicate that a proto-Anydros basin formed by progressive normal faulting along parallel to subparallel NE-SW-trending faults near the current Anydros basin and extending further to the SW through Santorini toward Christiana island (Figure 2.11b). A substantial portion of the proto-basin is currently filled by the Santorini volcanic edifice (bold black line, 33 Figure 2.4c) and the Kolumbo volcanic field (Figure 2.11b, 2.11d). Gravity and magnetic data support the presence of a NE-SW-oriented fault zone underlying the caldera (Figure 2.10) (Budetta et al., 1984). We infer that the proto-Anydros basin intersected the Christiana basin in the region of the SE Christiana sub-basin, potentially contributing to deepening of the SE portion of this sub-basin (Figure 2.8). During the Pleistocene (Figure 2.11c), volcanism initiated at Christiana Island (~1.2 Myr) (Piper et al., 2007) and was roughly localized at the intersection of the proto-Anydros basin with the Christiana basin (Figure 2.11c). Because the proto-Anydro basin is filled by the Santorini and Kolumbo edifices (Figure 2.11d), the NW-SE extension that formed this basin must have preceded the majority of these volcanic eruptions. Volcanism at Santorini began around the Middle Pleistocene (650 ka) (Figure 2.11c) (Druitt et al., 1999). Seismic reflection data show that the present-day Anydros basin opened in six tectonic pulses (Hübscher et al., 2015; Nomikou et al., 2016), creating the basin that is currently observed to the NE of Santorini. The exact relationship between Santorini volcanism and Anydros basin formation is not known though the seismic reflection data indicate that eruptions from nearby Kolumbo seamount started after Anydros basin initiation (Nomikou et al., 2018). Because all of the regional volcanism falls within the proto-Anydros basin (Figure 2.11d), it is likely that this basin has played a role in localizing volcanism. Such interaction between extension and volcanism is readily observed in analog models where volcanism is localized in rift basins during oblique extension (Corti et al., 2003). The above interpretations, where proto-Anydros basin formation precedes major local volcanism, are consistent with previous models that inferred that the rotation from older NNE-SSW extension to the current NW-SE extension in the 34 early Pliocene was associated with an increase in volcanism in the area (Piper et al., 2007). Across the Hellenic arc, volcanism is dominantly associated with NE- SW striking features (i.e. NW-SE extension) (e.g., Budetta et al., 1984) and only secondarily with NW-SE strikes (Kokkalas & Aydin, 2013). 2.6.3 Volcano-tectonic lineaments At Santorini we recover and improve on the geometry of the well-known Kameni and Kolumbo volcano-tectonic lineaments, using information inferred from the seismic tomography images (Figures 2.5, 2.8 and 2.10). The northern margin of the low-velocity anomaly (LVA ) within the Santorini caldera is bordered by the Kolumbo line, initially identified as an alignment of volcanic edifices in the northern portion of Santorini. It has been suggested that one of the vents of the LBA eruption was located along this line (Pfeiffer, 2001). In our study, the Kolumbo line is tomographically imaged at 3 km depth as a linear feature that divides a seismically fast region to the north from a lower velocity region to the south, oriented more northerly than suggested by previous studies and sub-parallel to the regional NE-SW trending faults (Figures 2.2 and 2.10). The tomographically defined Kolumbo lineament is associated with faulting observed in MCS profiles north of Kolumbo volcano (Figure A.10) (Nomikou et al., 2016). This line is also aligned with exposed dikes in the northern portion of the caldera walls and with a similarly oriented dike exposed on Therasia on the western side of the caldera (Browning et al., 2015; Fabbro et al., 2013). The joint interpretation of these observations suggests that (at depth) the Kolumbo line is controlled by regional tectonism and that it plays a dominant role in localizing magmatic and volcanic features, both within, and close to, Santorini. 35 In contrast to the Kolumbo line, the Kameni line has a weaker tomographic signature. This line, which is thought to have focused vents of prior explosive eruptions (Druitt et al., 1989), has previously been defined using the orientation of post-LBA eruption vents on the Kameni islands (Pyle and Elliott, 2006). Moreover, it was re-activated seismically in the recent 2011-2012 seismo-volcanic crisis (e.g. Newman et al., 2012), verifying its active character. Our study shows that the line is associated with a NE-SW trending region of limited lateral extent that divides anomalously slow velocities to the NW from faster velocities to the SE (Figure 2.10) and lies parallel to the tomographically recovered Kolumbo line. The Kameni and Kolumbo lines border the caldera LVA, a region of collapse in the northern caldera (Hooft et al., 2019). This isolated region of deepened caldera collapse, which overlies a recent influx of magma (e.g. Newman et al., 2012; Parks et al., 2015), seems to have been limited in extent by these tectono- magmatic lineaments. Similarly, the majority of exposed dikes and vents associated with Santorini volcanism also fall between the Kolumbo and Kameni lines. It is clear these lineaments have helped to control the tectonic evolution of the volcanic system and, given their association with eruptive vents, they have likely shaped magma input into the upper crust. 2.7 Conclusions We used the seismic velocity model to outline faults and basins (Figure 2.5) and to correlate magmatic and tectonic processes. In the Santorini region, we find that the tomographic results compare well with previous seismic reflection studies and geological outcroppings on Santorini (Figure 2.10). Geologically observed dikes and volcanic chains around the volcano directly overlie tomographically observed faults and tectono-magmatic lineations. Inside the caldera, volcanic vents and 36 deposits from the Late Bronze Age eruption correspond to a seismically slow region of caldera collapse. Our results and interpretations, combined with those from other studies, support the following conclusions: 1. Resolved tomographic structures, specifically orientations of faults and basins, are consistent with a previously proposed tectonic evolution model consisting of NNE-SSW extension during the Miocene-Pliocene transitioning to NW-SE extension in the Late Pliocene-Pleistocene that predominates on the eastern side of Santorini (Figure 2.11). This present-day extension is associated with pervasive faulting east of Santorini. 2. The Christiana, Santorini, and Kolumbo volcanic centers are found to lie in a NE-SW-trending basin-like structure, the proto-Anydros basin (Figure 2.5). These results are in agreement with models that suggest volcanism initiated after the transition to NW-SE extension in the Pleistocene. 3. Two tectono- magmatic lineaments control magma emplacement at Santorini. These lineaments border a NE-SW trending region of low velocity, are associated with dikes in the caldera walls, and strike parallel to active NE-SW trending regional faults and sub-parallel to regional volcanic chains. The two lineaments also bound a region of localized caldera collapse within Santorini’s northern caldera, verifying the strong relationship between tectonics and magmatism. 2.8 Bridge In Chapter II I outlined regional tectonic and magmatic features around Santorini Volcano, emphasizing that the magmatic features, which generally have a NE-SW orientation, have been localized in a buried NE-SW elongate basin. I proposed a simplified conceptual model for regional tectonic evolution and its association with this localized magmatism. In Chapter III, I discuss whether this localized magmatism results from small scale (km) faulting or regional tectonic 37 stresses. In addition, I investigate pervasive regional fracturing of the crust in this extensional tectonic environment. 38 CHAPTER III RELATIONSHIP BETWEEN FAULTING AND MAGMATISM AROUND SANTORINI: SEISMIC ANISOTROPY RESULTS FROM A REFRACTION EXPERIMENT This chapter is being prepared for future publication. Ben Heath conducted all inversions, drafted all figures (excluding portions of those credited to other sources) and wrote the manuscript. Emilie Hooft provided edits to a previous version of this chapter. Michele Paulatto and Joanna Morgan aided anisotropy interpretations as well as provided suggestions on the modeling of anisotropy. 3.1 Introduction Investigations of magmatic centers and their evolution show strong evidence that extensional tectonic and magmatic processes interact on regional ( ≥ O ( 101 ) km) and local (< O ( 101 ) km) scales. For example, volcanoes are often found to be located in areas of increased faulting near first-order, regional fault zones. In rifts, magmatism is often focused in regional-scale basins and vents are arranged in linear lines paralleling the orientation of fault zones (e.g. Casey et al., 2006; Muirhead et al., 2015). For areas such as the Basin and Range and the Aegean, magmatism is often found to focus at accommodation zones, complex zones of intermeshed faults (Faulds & Varga, 1998). In such regions, major normal faults often terminate in magmatic centers, either due to pre-existing magmatism inhibiting fault propagation or due to tectonic-induced stress distributions favorable to magma body development (Faulds & Varga, 1998). These observations all support a strong correlation between extension in faulted continental crust and magmatic activity. Despite this strong correlation, understanding of exactly how these processes are related remains enigmatic. For example, faults and fractures are thought 39 to represent permeability pathways through the crust and/or represent zones of crustal weakness characterized regionally by damaged host rock. In these models, dikes and their associated melt follow preexisting fracture networks, and therefore are focused to regions dominated by extensive fracturing, extensive damage and higher permeability (Kokkalas & Aydin, 2013). Other models suggest that magmatism accommodates extensional strain, inhibiting faulting (Parsons & Thompson, 1991) and that magmatism should therefore be associated with lessened faulting. Stress-based models suggest that dikes open approximately in the direction of least compressive stress, a direction that need not be associated with the shear-based faulting (Anderson, 1951; Gudmundsson, 1995). In these models, dikes follow solely a stress-based path and, therefore, a regional correlation between faulting and magmatism represents the shared dependence of both processes on stress. These processes are further complicated by the fact that magmatism and tectonism iteratively impact each other. For example, dikes can alter a tectonic stress field, leading to shallower angle faulting (Parsons & Thompson, 1993), which in turn alters the stress field leading to altered dike orientations. From observations it is clear that tectonism and magmatism are related, however why they are related is still an area of active research with models proposing multiple styles of interaction between tectonic and magmatic features. Here we use anisotropic P-wave travel-time tomography to investigate local and regional interaction between tectonism and magmatism at Santorini Volcano Greece. We investigate tectonic and magmatic sources of anisotropy, modeling the role of each in our observations. We highlight the relationship between local faults/fractures, regional tectonic features and magmatic features. Our results show how pervasive regional faulting has shaped the Aegean crust around Santorini. These results support the hypothesis that regional scale tectonic processes 40 dominate the relationship between tectonism and magmatism in extensional volcanic arcs such as the Aegean and that local-scale surface faulting neither controls, nor is controlled by, regional magmatic activity and is rather a product of local stress variations in the upper crust. 3.2 Background 3.2.1 Geologic Background of the Aegean The Aegean is characterized by extension dominated tectonic structures resulting from Oligocene/Miocene to present slab roll-back of the Hellenic subduction zone (Pichon & Angelier, 1979), westward extrusion of Anatolia (McKenzie, 1972), and gravitational collapse of continental crust (McKenzie, 1972). These structures weakened the crust, localizing deformation (Jolivet et al., 2013, and citations therein) and magmatism in the Cyclades (Kokkalas & Aydin, 2013) (Figure 3.1). Extensional detachments and NNE-trending strike-slip faults controlled Aegean pluton emplacement during the middle Miocene (Kokkalas & Aydin, 2013). In many cases, this pluton emplacement was associated with structural complexities that enhanced local permeability. This regional pluton emplacement, which occurred along zones of contemporaneous deformation, arrested in the late Pliocene when internal deformation of the Cycladic region ceased. Santorini lies at the margin of this non-deforming region (e.g. Le Pichon & Kreemer, 2010). Around Santorini during the Miocene to Pliocene, N-S extension created E- W-striking normal faults (Anastasakis & Piper, 2005; Piper et al., 2007). Activity on the main bounding faults of the basin ceased 1 Ma during the Pleistocene (Piper & Perissoratis, 2003) but some regional tectonic activity continues to present day as evidenced by small-offset faults (Tsampouraki-Kraounaki & Sakellariou, 41 25˚00' 25˚15' 25˚30' 25˚45' 26˚00' 36˚15' 36˚30' 36˚45' −1200 −800 −400 0 400 20˚ 22˚ 24˚ 26˚ 28˚ 30˚ 32˚ 34˚ 36˚ 38˚ 40˚ 42˚ Methana Milos Santorini Nisyros&Kos Aegean Greece Turkey Africa Hellenic Trough North Anatolia Fault Cyclades Anatolia Crete Cretan Basin Eastern Aegean volcanic arc volcano study area region of volcanism stretching lineation burie d horst acc ommodatio n zo ne Figure 3.1. a) Regional map of the Aegean showing the Hellenic subduction zone, Hellenic volcanic arc, as well as the Santorini study area, from Heath et al. (2019). Bold black lines represent regional faults. b) Topographic/bathymetric map showing the experiment geometry, shot locations (red dots) and seismic stations(yellow). Orange shaded regions mark regions of magmatism. White shaded arrows and lines represent stretching lineations recorded in metamorphic rocks from prior episodes of deformation (after Schneider et al. (2018). Red lines mark tectono-magmatic lineaments. 42 2018). These E-W striking normal faults are to first